4-Methylcyclohexanemethanol (MCHM, systematic name 4- methylcyclohexylmethanol) is an Eastman Chemical Company’s MSDS for ” crude” (unpurified) MCHM, as supplied by NPR, reports an oral LD of mg/ kg and a dermal LD Product Name. 4-Methylcyclohexanol, mixture of cis and trans. Cat No. Details of the supplier of the safety data sheet. Emergency Telephone. 4-Methylcyclohexanemethanol (cis- and trans- mixture) 1-(Hydroxymethyl)-4 -methylcyclohexane. 4. FIRST-AID MEASURES SAFETY DATA SHEET.
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4-Methylcyclohexanemethanol – Wikipedia
Languages Deutsch Edit links. Both cis and trans isomers exist, depending on the relative positions of the methyl CH 3 and hydroxymethyl CH 2 OH groups on the cyclohexane ring. Ullmann’s Encyclopedia of Industrial Chemistry.
Retrieved 19 January Journal of the Chemical Society, Transactions.
The toxicity and environmental properties of these naphthenic acids have been well studied recently due to their occurrence as a major contaminant jethanol water used for extraction of oil from tar sands. A WHO study concluded that p -menthanol was of “no safety concern” for human consumption at high levels of 2.
From Wikipedia, the free encyclopedia. CHM with a methylethyl or isopropyl substituent group at the same position as the methyl mrthanol in 4-methylcyclohexanemethanol cis 1-methylethyl cyclohexane methanol, CAS is regarded as a flavoring and fragrance agent, sometimes listed under the synonym p -menthanol, and was the subject of a review article on its toxicological and dermatological properties in However, a longer-term six-week repetition of that test as a sensitization study failed to produce any reactions.
Journal of the Chemical Society Resumed: This page was last edited on 10 Decemberat It was first prepared in by Bouveault—Blanc reduction of a methylcyclohexanecarboxylate ester.
MCHM has the advantage of being less toxic than previous frothing agents containing 2-ethylhexanol. Other cyclohexane -based alcohols can also be used. The closely related compound cyclohexanedimethanol CAS exhibits low toxicity 3.
US Patent Application No. The solubility of 1-octanol in water is 2. International Programme on Chemical Safety. It has been patented for use in air fresheners.
Other names 1- hydroxymethyl methylcyclohexane 4-methylcyclohexylcarbinol MCHM hexahydro- p -tolyl-carbinol archaic. Reliable information on health and safety of this compound is limited. Refractive index n D. It is a colourless oil with a faint mint-like alcohol odor. Retrieved from ” https: Commercial samples of MCHM consists of a mixture of these isomers as well as other components that vary with the supplier.
Retrieved 12 June Views Read Edit View history. Journal of Environmental Engineering and Science. Another CHM derivative, 2,4-dimethylcyclohexanemethanol CASalso dihydrofloralol or floral methanolwhich has two methyl substituents instead of one, is frequently marketed as a fragrance or flavor additive.
One web site, Fantastic Flavours provides a list of recognized flavor additives for Japan, which includes 2,4-dimethylcyclohexanemethanol by virtue of being in the group of aliphatic higher alcohols. The Two Way blog. Indian Journal of Microbiology.
It is also produced as a byproduct ca.
Cyclohexanemethanol or cyclohexylmethanolCHM, CASanother closely related compound, which differs only in lacking a methyl substituent, has been found as a naturally occurring fusel alcohol in mango wine at concentrations of 1. The ChemSpider entry for MCHM indicates that it has been evaluated for ligand activity via SimBioSys ‘s LASSO analysis, which predicted low to no activity on 40 biologically significant receptorsindicating a low likelihood for significant biological activity on them.
Epimeric alcohols of the cyclohexane series.